論文

査読有り
2016年5月

Synthesis and Chiroptical Properties of a Ring-Fused BODIPY with a Skewed Chiral π Skeleton

Organic Letters
  • Yuki,Gobo
  • ,
  • Masaki,Yamamura
  • ,
  • Takashi,Nakamura
  • ,
  • Tatsuya,Nabeshima

18
11
開始ページ
2719
終了ページ
2721
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1021/acs.orglett.6b01237
出版者・発行元
American Chemical Society

A twisted chiral boron-dipyrrin complex (BOD-IPY) was synthesized by oxidative annulation of the biphenyl units at the beta positions. The chiral BODIPY has two asymmetric carbons in the large planar skeleton, which Were generated upon the ring-fused reaction. Its pi-elongated and twisted structure resulted in the Cotton effect in the red region (lambda(max) = 614 nm, Delta epsilon = 60 M-1.cm(-1)) as well as the strong, fluorescence (Phi(F) = 0.73) and circularly polarized luminescence (CPL).

リンク情報
DOI
https://doi.org/10.1021/acs.orglett.6b01237