1985年
Dynamic behaviour of active sites of a Si02-attached Mo(VI)-dimer catalyst during ethanol oxidation observed by means of EXAFS
Zeitschrift fur Physikalische Chemie
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- 巻
- 144
- 号
- 144
- 開始ページ
- 105
- 終了ページ
- 115
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1524/zpch.1985.144.144.105
The dynamic behaviour of active sites of a Si02-attached Mo(VI)-dimer catalyst during ethanol oxidation were studied by means of EXAFS. Catalytic ethanol oxidation was found to proceed by cooperative catalysis of the two adjacent Mo ions of the dimer catalyst in conjunction with the reversible structural oscillation of the active sites (shortening⇄ expanding of Mo - Mo and Mo - O bonds). © 1985, R. Oldenbourg Verlag, München
- ID情報
-
- DOI : 10.1524/zpch.1985.144.144.105
- ISSN : 0942-9352
- SCOPUS ID : 84903307601