2018年7月
Catalytic Conversion of Biomass-Derived Carbohydrates to Methyl Lactate by Acid-Base Bifunctional gamma-Al2O3
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
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- 巻
- 6
- 号
- 7
- 開始ページ
- 8113
- 終了ページ
- 8117
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/acssuschemeng.8b00809
- 出版者・発行元
- AMER CHEMICAL SOC
We report the catalytic conversion of biomass-derived carbohydrates to methyl lactate using metal oxides. The combination of Lewis acid-base sites on gamma-Al2O3 is superior to several amphoteric oxides for the production of methyl lactate from both dihydroxyacetone and glucose in methanol. The successful production of methyl lactate from glucose by gamma-Al2O3 is attributed to high densities of both acid and base functionalities that are essential for the promotion of the stepwise reaction, which consists of isomerization, retro-aldol, and dehydration reactions.
- リンク情報
- ID情報
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- DOI : 10.1021/acssuschemeng.8b00809
- ISSN : 2168-0485
- Web of Science ID : WOS:000444924500005