2018年11月
Transformative reduction of carbon dioxide through organocatalysis with silanes
GREEN CHEMISTRY
- ,
- 巻
- 20
- 号
- 21
- 開始ページ
- 4834
- 終了ページ
- 4843
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1039/c8gc02052c
- 出版者・発行元
- ROYAL SOC CHEMISTRY
Carbon dioxide (CO2) is a promising feedstock for the synthesis of complex organic chemicals due to its abundancy, non-toxic nature, and favourable physical properties. However, CO2 is considered to be a chemically unattractive reagent due to its stability and high oxidation state. Thus, to increase the energy content of CO2 and improve its versatility as a reaction substrate, various organocatalysts have been developed based on the use of silane reducing agents. We herein present an overview of the development of organocatalysts for the reductive transformation of CO2 while emphasising the factors affecting the reactions, and summarising current insights into the mechanisms governing these reactions.
- リンク情報
- ID情報
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- DOI : 10.1039/c8gc02052c
- ISSN : 1463-9262
- eISSN : 1463-9270
- Web of Science ID : WOS:000452487400001