論文

査読有り
2018年11月

Transformative reduction of carbon dioxide through organocatalysis with silanes

GREEN CHEMISTRY
  • Pramuditaa, Ria Ayu
  • ,
  • Motokura, Ken

20
21
開始ページ
4834
終了ページ
4843
記述言語
英語
掲載種別
DOI
10.1039/c8gc02052c
出版者・発行元
ROYAL SOC CHEMISTRY

Carbon dioxide (CO2) is a promising feedstock for the synthesis of complex organic chemicals due to its abundancy, non-toxic nature, and favourable physical properties. However, CO2 is considered to be a chemically unattractive reagent due to its stability and high oxidation state. Thus, to increase the energy content of CO2 and improve its versatility as a reaction substrate, various organocatalysts have been developed based on the use of silane reducing agents. We herein present an overview of the development of organocatalysts for the reductive transformation of CO2 while emphasising the factors affecting the reactions, and summarising current insights into the mechanisms governing these reactions.


リンク情報
DOI
https://doi.org/10.1039/c8gc02052c
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000452487400001&DestApp=WOS_CPL
ID情報
  • DOI : 10.1039/c8gc02052c
  • ISSN : 1463-9262
  • eISSN : 1463-9270
  • Web of Science ID : WOS:000452487400001

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