論文

査読有り
2019年11月

Silica-supported Alkylammonium Formate Catalyst for Hydrosilylation of Carbon Dioxide

CHEMISTRY LETTERS
  • Pramudita, Ria Ayu
  • ,
  • Nakagawa, Chihiro
  • ,
  • Manaka, Yuichi
  • ,
  • Motokura, Ken

48
11
開始ページ
1417
終了ページ
1420
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1246/cl.190649
出版者・発行元
CHEMICAL SOC JAPAN

An amorphous silica-supported alkylammonium formate catalyst for the reductive transformation of carbon dioxide using silane as a reductant was developed. Alkylammonium iodide was grafted on amorphous silica, followed by anion exchange of iodide to formate. The successful synthesis of the catalyst was confirmed by solid-state (CCP)-C-13/MASNMR spectroscopy, FT-IR spectroscopy, and elemental analysis. While silica-supported alkylammonium formate exhibited catalytic activity in the hydrosilylation of CO2 to generate silylformate as the main product, no catalytic activity was observed in the presence of silica-supported alkylammonium iodide.


リンク情報
DOI
https://doi.org/10.1246/cl.190649
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000495894300027&DestApp=WOS_CPL
ID情報
  • DOI : 10.1246/cl.190649
  • ISSN : 0366-7022
  • eISSN : 1348-0715
  • Web of Science ID : WOS:000495894300027

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