2019年11月
Silica-supported Alkylammonium Formate Catalyst for Hydrosilylation of Carbon Dioxide
CHEMISTRY LETTERS
- ,
- ,
- ,
- 巻
- 48
- 号
- 11
- 開始ページ
- 1417
- 終了ページ
- 1420
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1246/cl.190649
- 出版者・発行元
- CHEMICAL SOC JAPAN
An amorphous silica-supported alkylammonium formate catalyst for the reductive transformation of carbon dioxide using silane as a reductant was developed. Alkylammonium iodide was grafted on amorphous silica, followed by anion exchange of iodide to formate. The successful synthesis of the catalyst was confirmed by solid-state (CCP)-C-13/MASNMR spectroscopy, FT-IR spectroscopy, and elemental analysis. While silica-supported alkylammonium formate exhibited catalytic activity in the hydrosilylation of CO2 to generate silylformate as the main product, no catalytic activity was observed in the presence of silica-supported alkylammonium iodide.
- リンク情報
- ID情報
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- DOI : 10.1246/cl.190649
- ISSN : 0366-7022
- eISSN : 1348-0715
- Web of Science ID : WOS:000495894300027