論文

査読有り
2019年

Carbon Dioxide to Organic Compounds Assisted by Silanes: Successive Transformation of Silyl Formate to Various Products

JOURNAL OF THE JAPAN PETROLEUM INSTITUTE
  • Motokura, Ken
  • ,
  • Pramudita, Ria Ayu
  • ,
  • Manaka, Yuichi

62
6
開始ページ
255
終了ページ
263
記述言語
英語
掲載種別
DOI
10.1627/jpi.62.255
出版者・発行元
JAPAN PETROLEUM INST

This review paper summarizes the recent advances in the transformation of silyl formate to various organic compounds using one-pot processes. Silyl formate can be synthesized from CO2 and hydrosilane via hydrosilylation. Recently, many catalysts have been developed for CO2 conversion to silyl formate, resulting in the increasing importance of further conversion of silyl formate. A number of conversion reactions of silyl formate are introduced, including hydration, ester formation, amide formation, salt production, carbon-carbon bond formation, and metal carbonyl complex formation. These reactions smoothly proceed because of the high reactivity and electrophilicity of silyl formate. In some cases, the scope of the reaction partners, such as alcohols and amines, will also be discussed.


リンク情報
DOI
https://doi.org/10.1627/jpi.62.255
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000493897700002&DestApp=WOS_CPL
ID情報
  • DOI : 10.1627/jpi.62.255
  • ISSN : 1346-8804
  • eISSN : 1349-273X
  • Web of Science ID : WOS:000493897700002

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