論文

査読有り
2019年7月

Rh-catalyzed 1,4-addition reactions of arylboronic acids accelerated by co-immobilized tertiary amine in silica mesopores

MOLECULAR CATALYSIS
  • Motokura, Ken
  • ,
  • Hashiguchi, Kohei
  • ,
  • Maeda, Kyogo
  • ,
  • Nambo, Masayuki
  • ,
  • Manaka, Yuichi
  • ,
  • Chun, Wang-Jae

472
開始ページ
1
終了ページ
9
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1016/j.mcat.2019.04.016
出版者・発行元
ELSEVIER SCIENCE BV

Mesoporous silica-supported Rh complex catalysts were prepared by simple silane-coupling, followed by cornplexation, and characterized by FT-IR, SEM, Rh K-edge XAFS, and elemental analysis. Local structures of the Rh complexes in each sample were almost similar to those of a nonporous silica-supported diaminorhodiurn complex. Co-immobilization of a tertiary amine on the same silica surface induced slight changes to the Rh complex structure in the case of the support with smaller pores. The prepared catalysts showed high activity for the 1,4 addition reaction of phenylboronic acids. Co-immobilization of the tertiary amine increased the reaction rate by more than 7-fold, with turnover number of nearly 8500. The catalytic performance achieved with this novel system is with much higher than that reported previously with a nonporous silica-supported catalyst. The mesoporous silica-supported Rh complex-tertiary amine showed a wide substrate scope, including unsaturated ketones and nitriles. This co-immobilized tertiary amine may activate phenylboronic acid to enhance its reactivity in the transmetalation step with Rh-OH species.


リンク情報
DOI
https://doi.org/10.1016/j.mcat.2019.04.016
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000472687900001&DestApp=WOS_CPL
ID情報
  • DOI : 10.1016/j.mcat.2019.04.016
  • ISSN : 2468-8231
  • Web of Science ID : WOS:000472687900001

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