2020年11月20日
Intermolecular Oxidative Friedel–Crafts Reaction Triggered Ring Expansion Affording 9,10-Diarylphenanthrenes
Organic Letters
- ,
- ,
- ,
- 巻
- 22
- 号
- 13
- 開始ページ
- 8920
- 終了ページ
- 8924
- 記述言語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/acs.orglett.0c03283
- 出版者・発行元
- American Chemical Society ({ACS})
A novel intermolecular tandem oxidative aromatic coupling between arylidene fluorenes and unfunctionalized aromatics mediated by a DDQ/TFA oxidation system has been developed for the construction of 9,10-diary-lphenanthrenes (DAPs). The formation of a benzylic carbocation species possessing a quaternary sp3-carbon center on the fluorene moiety by an intermolecular oxidative Friedel-Crafts reaction of two different arenes successfully triggered the subsequent ring expansion to afford DAPs.
- リンク情報
- ID情報
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- DOI : 10.1021/acs.orglett.0c03283
- ISSN : 1523-7060
- eISSN : 1523-7052
- ORCIDのPut Code : 82949150
- PubMed ID : 33147023
- SCOPUS ID : 85096509057