MISC

2011年9月

Elastic moduli of Ce0.9Gd0.1O2-delta at high temperatures under controlled atmospheres

SOLID STATE IONICS
  • Koji Amezawa
  • ,
  • Takuto Kushi
  • ,
  • Kazuhisa Sato
  • ,
  • Atsushi Unemoto
  • ,
  • Shin-ichi Hashimoto
  • ,
  • Tatsuya Kawada

198
1
開始ページ
32
終了ページ
38
記述言語
英語
掲載種別
DOI
10.1016/j.ssi.2011.07.009
出版者・発行元
ELSEVIER SCIENCE BV

The Young's modulus and the shear modulus of Ce0.9Gd0.1O2 - delta (GDC) were evaluated by using a resonance method in the temperature range from room temperature to 1273 K and in the p(O-2) range from 10(-24) to bar. It was found that the elastic moduli of GDC under oxidizing conditions gradually decreased with increasing temperature in a constant atmosphere and was almost independent of p(O-2) at a constant temperature. However, under reducing conditions, the elastic moduli apparently decreased as p(O-2) decreased even at a constant temperature, and such a decrease became more considerable under lower p(O-2) conditions. The variation in the elastic moduli of GDC with p(O-2) seemed to reflect the variation in the oxygen nonstoichiometry delta. It was demonstrated that the elastic moduli are affected not only by the change in the interatomic distance due to the chemical and/or the thermal expansion but also by the variation in the oxygen nonsotichiometry and the average valence of cerium ions. (C) 2011 Elsevier B.V. All rights reserved.

リンク情報
DOI
https://doi.org/10.1016/j.ssi.2011.07.009
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000295892700006&DestApp=WOS_CPL
ID情報
  • DOI : 10.1016/j.ssi.2011.07.009
  • ISSN : 0167-2738
  • Web of Science ID : WOS:000295892700006

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