SEINO Hidetake

Last updated: Nov 8, 2018 at 13:17

Name	SEINO Hidetake
Affiliation	Akita University
Section	Faculty of Education and Human Studies
Job title	Research Assistant
Research funding number	50292751
ORCID ID	0000-0002-8792-1974

Research Interests

Nitrogen fixation(18) , Metal clusters(4) , Organometallics(14) , Transition metal complexes(7)

Research Areas

Chemistry / Organic chemistry /
Chemistry / Inorganic chemistry /
Applied Chemistry / Synthetic chemistry /

Academic & Professional Experience

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Apr 2013

Today

Associate Professor, Faculty of Education and Human Studies, Akita University

Apr 2011

Mar 2013

Assistant Professor, Research Center for Sustainable Materials, Institute of Industrial Science, The University of Tokyo

Apr 2007

Mar 2011

Assistant Professor, Institute of Industrial Science, The University of Tokyo

Apr 1997

Mar 2007

Research Associate, Institute of Industrial Science, The University of Tokyo

Education

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Apr 1994

Mar 1997

Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo

Apr 1992

Mar 1994

Department of Synthetic Chemistry, Graduate School of Engineering, The University of Tokyo

Apr 1988

Mar 1992

Department of Industrial Chemistry, Faculty of Engineering, The University of Tokyo

Published Papers

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Reversible Hydride Transfer to N,N′-Diarylimidazolinium Cations from Hydrogen Catalyzed by Transition Metal Complexes Mimicking the Reaction of [Fe]-Hydrogenase

Masahiro Hatazawa, Naoko Yoshie, Hidetake Seino

Inorganic Chemistry 56(14) 8087 Jun 2017 [Refereed]

Structural Determination, DFT Calculation, and Formation Mechanism of Ethyl 2-Cyano-3-alkoxypent-2-enoates Synthesized via Ru-Mediated Coupling Reaction between α,β-Unsaturated Acetals and Cyanoacetate

Hidetake Seino, Takumi Kondo, Chihiro Mochizuki, Ken Tokunaga, Motowo Yamaguchi, Mitsunobu Sato

Bulletin of the Chemical Society of Japan 90(1) 79 Jan 2017 [Refereed]

Synthesis and Protonation of N-Heterocyclic-Carbene-Supported Dinitrogen Complexes of Molybdenum(0)

Yasuhiro Ohki, Keiya Aoyagi, Hidetake Seino

Organometallics 34(13) 3414 Jul 2015 [Refereed]

Photooxidation and Photoluminescence of Triarylmethane Dye-Conjugated Zinc Complexes: Optical Anisotropy and Optical Activity Emerging from Distinct Crystal Packing Modes

Saori Takeda, Hiroka Yamada, Shunpei Takezawa, Isao Yoshikawa, Hidetake Seino, Kazunari Matsumura, Hirohiko Houjou

Bulletin of the Chemical Society of Japan 88(5) 698 May 2015 [Refereed]

Linear Connection of Four Nitrile Molecules on the Tetraphosphine Complexes of Tungsten and Molybdenum

Qi Xiu Dai, Hidetake Seino, Yasushi Mizobe

Organometallics 33(13) 3652 Jul 2014 [Refereed]

Polymers with Multishape Memory Controlled by Local Glass Transition Temperature

Chao Zeng, Hidetake Seino, Jie Ren, Naoko Yoshie

ACS Applied Materials & Interfaces 6(4) 2753 Feb 2014 [Refereed]

Peptide-catalyzed kinetic resolution of planar-chiral metallocenes

Midori Akiyama, Kengo Akagawa, Hidetake Seino, Kazuaki Kudo

Chem. Commun. 50(58) 7893 2014 [Refereed]

A molybdenum complex bearing a tetraphosphine ligand as a precursor for heterobimetallic complexes

Ryoga Yasuda, Kentaro Iwasa, Fumiya Niikura, Hidetake Seino, Yasushi Mizobe

Dalton Transactions 43(24) 9344 2014 [Refereed]

Self-healing bio-based furan polymers cross-linked with various bis-maleimides

Chao Zeng, Hidetake Seino, Jie Ren, Kenichi Hatanaka, Naoko Yoshie

Polymer 54(20) 5351 Sep 2013 [Refereed]

Bio-Based Furan Polymers with Self-Healing Ability

Chao Zeng, Hidetake Seino, Jie Ren, Kenichi Hatanaka, Naoko Yoshie

Macromolecules 46(5) 1794 Mar 2013 [Refereed]

Tungsten(II) Alkylimido Complexes from Insertion of Nitriles into Tungsten Hydride: Alkylideneamido Intermediate Stage and Nitrene Group Transfer to Isocyanide

Qi Xiu Dai, Hidetake Seino, Yasushi Mizobe

Organometallics 31(14) 4933 Jul 2012 [Refereed]

Blue/Red Linear Dichroic Emission from a Highly Anisotropic Crystal of Triarylmethane Dye Conjugated with Phenoxo-Zinc Complexes

Hirohiko Houjou, Shunpei Takezawa, Issei Oyamada, Kazunari Matsumura, Hidetake Seino, Isao Yoshikawa, Yasushi Mizobe, Koji Araki

Chemistry - A European Journal 17(4) 1122-1127 Jan 2011 [Refereed]

Houjou H, Takezawa S, Oyamada I, Matsumura K, Seino H, Yoshikawa I, Mizobe Y, Araki K, Chemistry (Weinheim an der Bergstrasse, Germany), 2011, vol. 17, no. 4, pp. 1122-1127, 2011

Preparation of Incomplete Cubane-Type Ru2M(μ3-S)(μ2-Cl)3Clusters (M = Sb, Bi) and Isolation of the Ru2Sb Cluster Having a Novel μ3-SO Ligand. Functions in Oxygen Atom Transfer and Catalytic Oxidation of PPh3to O═PPh3by Molecular O2

Kazumasa Oya, Hidetake Seino, Midori Akiizumi, Yasushi Mizobe

Organometallics 30(11) 2939 Jun 2011 [Refereed]

Transformations of aryl isothiocyanates on tetraphosphine tungsten complexes and reactivity of the resulting dithiocarbonimidate ligand

Qi Xiu Dai, Hidetake Seino, Yasushi Mizobe

Dalton Transactions 40(44) 11822-11830 Nov 2011 [Refereed]

Dai QX, Seino H, Mizobe Y, Dalton transactions (Cambridge, England : 2003), 2011, vol. 40, no. 44, pp. 11822-11830, 2011

Preparation and Reactions of Molybdenum and Tungsten Hydride Complexes Containing the Tetraphosphane Ligand meso-o-C6H4(PPhCH2CH2PPh2)2

Qi Xiu Dai, Hidetake Seino, Yasushi Mizobe

European Journal of Inorganic Chemistry 2011(1) 141 Nov 2010 [Refereed]

Core Conversion Reactions of the Cubane-Type Metal-Sulfido Clusters: Shape Shift, Contraction, and Expansion of the MM′Re2S4Cubanes (M = Ir, Rh, Ru; M′ = Pt, Pd)

Rie Shibata, Hidetake Seino, Shunpei Fujii, Yasushi Mizobe

Inorganic Chemistry 49(15) 6889-6896 Aug 2010 [Refereed]

Shibata R, Seino H, Fujii S, Mizobe Y, Inorganic chemistry, 2010, vol. 49, no. 15, pp. 6889-6896, 2010

Heterolytic H2 activation by rhodium thiolato complexes bearing the hydrotris(pyrazolyl)borato ligand and application to catalytic hydrogenation under mild conditions

Hidetake Seino, Yoshiyuki Misumi, Yoshihiro Hojo, Yasushi Mizobe

Dalton Transactions 39(12) 3072-3082 Mar 2010 [Refereed]

Seino H, Misumi Y, Hojo Y, Mizobe Y, Dalton transactions (Cambridge, England : 2003), 2010, vol. 39, no. 12, pp. 3072-3082, 2010

Incorporation of Fe into the void corner of the incomplete cubane-type Ir3S(SH)3 sulfido-hydrosulfido cluster to give new cubane-type Ir3FeS4 clusters

Hidetake Seino, Hiroyuki Mori, Aya Shinozaki, Yasushi Mizobe

Journal of Organometallic Chemistry 695(15-16) 1878 Jul 2010 [Refereed]

Reactions of Bis(chalcogenolato) Complexes [(η5-C5Me5)Ir(CO)(ETol)2] (E = Se, S; Tol =p-Tolyl) with [Pt(PPh3)3]. Formation of Tri- or Dinuclear Mixed-Metal Complexes with Bridging Chalcogenido or Chalcogenolato Ligands

Takafumi Nakagawa, Hidetake Seino, Yasushi Mizobe

Organometallics 29(10) 2254 May 2010 [Refereed]

Theoretical Study on Activation and Protonation of Dinitrogen on Cubane-Type MIr3S4Clusters (M = V, Cr, Mn, Fe, Co, Ni, Cu, Mo, Ru, and W)

Hiromasa Tanaka, Fumihiro Ohsako, Hidetake Seino, Yasushi Mizobe, Kazunari Yoshizawa

Inorganic Chemistry 49(5) 2464-2470 Mar 2010 [Refereed]

Tanaka H, Ohsako F, Seino H, Mizobe Y, Yoshizawa K, Inorganic chemistry, 2010, vol. 49, no. 5, pp. 2464-2470, 2010

Reactions of Dienes with a Mo(0) Complex with Tetraphosphine Coligand [Mo(P4)(Ph2PCH2CH2PPh2)] (P4 =Meso-o-C6H4(PPhCH2CH2PPh2)2)

Hidetake Seino, Yasushi Mizobe

Journal of the Chinese Chemical Society 57(2) 135 Apr 2010 [Refereed]

A series of multinuclear homo- and heterometallic complexes with bridging tellurolato ligands derived from [Cp∗Ir(CO)(TeTol)2] (Cp∗=η5-C5Me5, Tol=p-tolyl)

Takafumi Nakagawa, Hidetake Seino, Yasushi Mizobe

Journal of Organometallic Chemistry 695(1) 137 Jan 2010 [Refereed]

Syntheses of new Mo(II) and W(II) mono(hydrosulfido) complexes and their conversion into di- and tetranuclear sulfido-bridged heterobimetallic complexes

Kentaro Iwasa, Hidetake Seino, Yasushi Mizobe

Journal of Organometallic Chemistry 694(23) 3775 Nov 2009 [Refereed]

Heterolytic Cleavage of Hydrogen Molecule by Rhodium Thiolate Complexes That Catalyze Chemoselective Hydrogenation of Imines under Ambient Conditions

Yoshiyuki Misumi, Hidetake Seino, Yasushi Mizobe

Journal of the American Chemical Society 131(41) 14636-14637 Oct 2009 [Refereed]

Misumi Y, Seino H, Mizobe Y, Journal of the American Chemical Society, 2009, vol. 131, no. 41, pp. 14636-14637, 2009

A series of thiolato-bridged di- and trinuclear complexes derived from [Tp∗Rh(SPh)2(MeCN)] (Tp∗=hydrotris(3,5-dimethylpyrazol-1-yl)borate)

Yoshiyuki Misumi, Hidetake Seino, Yasushi Mizobe

Inorganica Chimica Acta 362(12) 4409 Sep 2009 [Refereed]

Synthesis and characterization of a novel imidazole cyclic trimer

Petty Sukarsaatmadja, Tadamichi Kumabe, Kazuki Ishida, Hidetake Seino, Yasushi Mizobe, Naoko Yoshie

Tetrahedron Letters 50(28) 4135 Jul 2009 [Refereed]

Preparation, Structures, and Some Reactivities of Five-Coordinate Alkyne Complexes of Mo with Tetraphosphine or Diphosphine Coligand [Mo(RCCR′){meso-o-C6H4(PPhCH2CH2PPh2)2}] and [Mo(RCCR′)(Ph2PCH2CH2PPh2)2]

Fumiya Niikura, Hidetake Seino, Yasushi Mizobe

Organometallics 28(4) 1112 Feb 2009 [Refereed]

Preparation of a bis(hydrosulfido) complex of Mo having a tetraphosphine co-ligand and its transformation into MoRh2 and MoIr2 mixed-metal sulfido clusters

Kentaro Iwasa, Hidetake Seino, Fumiya Niikura, Yasushi Mizobe

Dalton Transactions (31) 6134 2009 [Refereed]

C–S bond cleavage of 2-methoxythiophene by Ir–TMEDA complex (TMEDA=N,N,N’,N’-tetramethylethylenediamine). Formation of novel dinuclear iridathiacyclohexenyl complex

Kentaro Iwasa, Hidetake Seino, Yasushi Mizobe

Journal of Organometallic Chemistry 693(19) 3197 Sep 2008 [Refereed]

DFT Study on Chemical N2Fixation by Using a Cubane-Type RuIr3S4Cluster: Energy Profile for Binding and Reduction of N2to Ammonia via Ru−N−NHx(x= 1−3) Intermediates with Unique Structures

Hiromasa Tanaka, Hiroyuki Mori, Hidetake Seino, Masanobu Hidai, Yasushi Mizobe, Kazunari Yoshizawa

Journal of the American Chemical Society 130(28) 9037 Jul 2008 [Refereed]

Properties and Reactivities of the Hydrido Ligands in Iridium Sulfido Clusters Relevant to Activation and Production of H2

Hidetake Seino, Akihiro Saito, Hidenobu Kajitani, Yasushi Mizobe

Organometallics 27(6) 1275 Mar 2008 [Refereed]

Reactions of Mo(II)-tetraphosphine complex [MoCl2{meso-o-C6H4(PPhCH2CH2PPh2)2}] with a series of small molecules

Takeshi Ohnishi, Hiroko Tsuboi, Hidetake Seino, Yasushi Mizobe

Journal of Organometallic Chemistry 693(2) 269 Jan 2008 [Refereed]

N−N Bond Cleavage of Organohydrazines by Molybdenum(II) and Tungsten(II) Complexes Containing a Linear Tetraphosphine Ligand. Formation of Nitrido or Imido Complexes and Their Reactivities

Daisuke Watanabe, Sumie Gondo, Hidetake Seino, Yasushi Mizobe

Organometallics 26(20) 4909 Sep 2007 [Refereed]

Synthesis of a Sulfido-Capped Trinuclear Cluster [{(η5-C5Me5)Ir}2{Mo(CO)3}(μ3-S)2] and Its Reactions at the Molybdenum Site Forming a Series of Ir2MoS2Clusters

Hidenobu Kajitani, Hidetake Seino, Yasushi Mizobe

Organometallics 26(14) 3499 Jul 2007 [Refereed]

Isolation of a Cubane-Type Metal Sulfido Cluster with a Molecular Nitrogen Ligand

Hiroyuki Mori, Hidetake Seino, Masanobu Hidai, Yasushi Mizobe

Angewandte Chemie International Edition 46(28) 5431 Jul 2007 [Refereed]

Isolation of a Cubane-Type Metal Sulfido Cluster with a Molecular Nitrogen Ligand

Hiroyuki Mori, Hidetake Seino, Masanobu Hidai, Yasushi Mizobe

Angewandte Chemie 119(28) 5527 Jul 2007 [Refereed]

Mo and W Dihalide Complexes with Uncommon Trigonal-Prismatic Geometry Imposed by the Linear Tetraphosphine Ancillary Ligand and Their Reactivities toward Diazoalkanes

Hidetake Seino, Daisuke Watanabe, Takeshi Ohnishi, Chirima Arita, Yasushi Mizobe

Inorganic Chemistry 46(12) 4784 Jun 2007 [Refereed]

Synthesis and X-ray structures of heptanuclear and decanuclear mixed-metal sulfido clusters containing noble metals and Group 15 metals

Kazumasa Oya, Takahiko Amitsuka, Hidetake Seino, Yasushi Mizobe

Journal of Organometallic Chemistry 692(1-3) 20 Jan 2007 [Refereed]

DFT Analysis of Cubane-Type FeIr3S4Clusters. Dinitrogen Binding and Activation at the Tetrahedral Fe Site

Pawel M. Kozlowski, Yoshihito Shiota, Satomi Gomita, Hidetake Seino, Yasushi Mizobe, Kazunari Yoshizawa

Bulletin of the Chemical Society of Japan 80(12) 2323 2007 [Refereed]

Synthesis of Tellurido-Bridged IrPt2, IrPd2, and IrPtPd Clusters by Inserting Zero-Valent Pt and Pd Centers into Te–C Bonds

Takafumi Nakagawa, Hidetake Seino, Shoken Nagao, Yasushi Mizobe

Angewandte Chemie International Edition 45(46) 7758 Nov 2006 [Refereed]

Synthesis of Tellurido-Bridged IrPt2, IrPd2, and IrPtPd Clusters by Inserting Zero-Valent Pt and Pd Centers into Te–C Bonds

Takafumi Nakagawa, Hidetake Seino, Shoken Nagao, Yasushi Mizobe

Angewandte Chemie 118(46) 7922 Nov 2006 [Refereed]

Addition of benzenethiol to terminal alkynes catalyzed by hydrotris(3,5-dimethylpyrazolyl)borate–Rh(III) bis(thiolate) complex: Mechanistic studies with characterization of the key intermediate

Yoshiyuki Misumi, Hidetake Seino, Yasushi Mizobe

Journal of Organometallic Chemistry 691(14) 3157 Jul 2006 [Refereed]

Mixed-Metal Sulfido Clusters Containing Noble Metals and Group 15 Metals. Stepwise Construction of Bimetallic and Trimetallic Ru2MS2(M = Sb, Bi), Ru2PdSbS2, and Ru2Pd2SbS2Cores

Takahiko Amitsuka, Hidetake Seino, Masanobu Hidai, Yasushi Mizobe

Organometallics 25(12) 3034 Jun 2006 [Refereed]

DFT Calculations of Cubane-Type Mo2Ru2S4Clusters. Stability of a Possible Dinitrogen Cluster and an Isolable Acetonitrile Cluster

Kazunari Yoshizawa, Naoki Kihara, Yoshihito Shiota, Hidetake Seino, Yasushi Mizobe

Bulletin of the Chemical Society of Japan 79(1) 53 Jan 2006 [Refereed]

Synthesis of sulfido- and thiolato-bridged Ir3 cluster and its reactions with alkyne and isocyanide including highly regioselective cyclotrimerization of methyl propiolate

Akihiro Saito, Hidetake Seino, Hidenobu Kajitani, Fusao Takagi, Akihito Yashiro, Takeshi Ohnishi, Yasushi Mizobe

Journal of Organometallic Chemistry 691(26) 5746 2006 [Refereed]

Preparation of Rhodium Pentasulfido(2−) Complexes with Hydrotris(3,5-dimethylpyrazol-1-yl)borato Coligand

Shoken Nagao, Nobuyuki Saito, Aiko Kojima, Hidetake Seino, Yasushi Mizobe

Bulletin of the Chemical Society of Japan 78(9) 1641 Sep 2005 [Refereed]

Preparation and structures of the cluster dimers consisting of Rh2Mo2S4 single-cubane units connected by two bidentate N-donor ligands

Tomoko Fujimura, Hidetake Seino, Masanobu Hidai, Yasushi Mizobe

Inorganica Chimica Acta 358(7) 2449 Apr 2005 [Refereed]

The CO and CS bond cleavage in carbon dioxide and tolyl isothiocyanate by reactions with the Mo(0) tetraphosphine complex [Mo{meso-o-C6H4(PPhCH2CH2PPh2)2}(Ph2PCH2CH2PPh2)]

Takeshi Ohnishi, Hidetake Seino, Masanobu Hidai, Yasushi Mizobe

Journal of Organometallic Chemistry 690(5) 1140 Mar 2005 [Refereed]

Synthesis of a Sulfido- and Thiolato-Bridged Trinuclear Bimetallic Cluster [{(η5-C5Me5)Ir}2{(η5-C5H5)Ru}Cl(μ3-S)(μ2-SCH2CH2CN)2] and Its Reactions with CO, Isocyanide, and Alkyne

Hidenobu Kajitani, Hidetake Seino, Yasushi Mizobe

Organometallics 24(25) 6260 2005 [Refereed]

Preparation of chalcogenolato-bridged dinuclear Tp*Rh–Cp*Ru complexes (Tp*= hydrotris(3,5-dimethylpyrazol-1-yl)borate, Cp*=η5-pentamethylcyclopentadienyl) and binding of dioxygen to their Ru sites

Shoken Nagao, Hidetake Seino, Masanobu Hidai, Yasushi Mizobe

Dalton Transactions (19) 3166 2005 [Refereed]

Misc

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Transition metal–sulfido clusters and nitrogen fixation

SEINO Hidetake

Sulfuric Acid and Industry 71(3) 1-13 Mar 2018 [Invited]

N-Heterocyclic carbenes as supporting ligands in transition metal complexes of N2

Yasuhiro Ohki, Hidetake Seino

Dalton Trans. 45(3) 874 2016 [Invited]

Catalytic functions of cubane-type M4S4 clusters

Hidetake Seino, Masanobu Hidai

Chemical Science 2(5) 847 2011 [Invited]

Ammonia Synthesis-Homogeneous

Encyclopedia of Catalysis Nov 2010 [Invited]

CHAPTER 10.1. Metal–Sulfur Clusters as the Model for the Active Sites of Metalloenzymes

Yasushi Mizobe, Hidetake Seino

Handbook of Chalcogen Chemistry : New Perspectives in Sulfur, Selenium and Tellurium 7 [Invited]

Conference Activities & Talks

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Differentiation of the ruthenium sites in cubane-type Ru4S4 clusters

H. Seino, N. Shindo, S. Kanai, M. Okazaki

The 43rd International Conference on Coordination Chemistry 4 Aug 2018

Metal-Catalyzed Reactions of N,N’-Disubstituted Imidazolinium Cations with Hydrogen as Functional Models of Hydrogenases in Methanogenesis

H Seino, M. Hatazawa, Y. Hojo, H. Suzuki, K. Takahashi, Y. Mizobe, N. Yoshie

Pacifichem2015 15 Dec 2015

Reactions of Cubane-type MoIr3S4 and TaIr3S4 Clusters with Hydrazine Compounds

Hidetake Seino, Yusuke Shibata, Yuta Manaka, Yasushi Mizobe

The 40th International Conference on Coordination Chemistry 12 Sep 2012

Syntheses of the Cubane-Type Transition-Metal Sulfido Clusters for Activation of Molecular Dinitrogen [Invited]

Hidetake Seino

The 14th International Conference on Biological Inorganic Chemistry (ICBIC14) 26 Jul 2009

Association Memberships

THE SOCIETY OF POLYMER SCIENCE, JAPAN(827) , American Chemical Society(1014) , JAPAN SOCIETY OF COORDINATION CHEMISTRY(211) , KINKI CHEMICAL SOCIETY, JAPAN(97) , Catalysis Society of Japan(346) , The Chemical Society of Japan(2710)

Research Grants & Projects

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