論文

査読有り
2014年2月

Polymers with Multishape Memory Controlled by Local Glass Transition Temperature

ACS APPLIED MATERIALS & INTERFACES
  • Chao Zeng
  • ,
  • Hidetake Seino
  • ,
  • Jie Ren
  • ,
  • Naoko Yoshie

6
4
開始ページ
2753
終了ページ
2758
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1021/am405287p
出版者・発行元
AMER CHEMICAL SOC

A multishape memory polymer with flexible design fabricated by a very simple method. Local glass transition temperatures of a loosely cross-linked polymer film are changed by immersing sections of the film in a cross-linker solution with a different concentration. Each section memorizes a temporary shape, which recovers its permanent shape at a different recovery temperature depending on the local glass transition temperature. As a base polymer, we chose a network polymer prepared by a Diels-Alder reaction between poly(2,5-furandimethylene succinate) (PFS) and 1,8-bis-maleimidotriethyleneglycol (M-2). Quintuple shape memory behavior was demonstrated by a PFS/M film with four sections with distinct glass transition temperatures. The number of temporary shapes was determined by the number of different M-2 solutions. Furthermore, owing to the reversibility of the Diels-Alder reaction, the permanent shape was rewritable.

リンク情報
DOI
https://doi.org/10.1021/am405287p
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000332144600072&DestApp=WOS_CPL
URL
http://orcid.org/0000-0002-8792-1974
ID情報
  • DOI : 10.1021/am405287p
  • ISSN : 1944-8244
  • ORCIDのPut Code : 31314388
  • Web of Science ID : WOS:000332144600072

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