2011年6月
Gd-2@C79N: Isolation, Characterization, and Monoadduct Formation of a Very Stable Heterofullerene with a Magnetic Spin State of S=15/2
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- 巻
- 133
- 号
- 25
- 開始ページ
- 9741
- 終了ページ
- 9750
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/ja202011u
- 出版者・発行元
- AMER CHEMICAL SOC
The dimetallic endohedral heterofullerene (EHF), Gd-2@C79N, was prepared and isolated in a relatively high yield when compared with the earlier reported heterofullerene, Y-2@C79N. Computational (DFT), chemical reactivity, Raman, and electrochemical studies all suggest that the purified Gd-2@C79N, with the heterofullerene cage, (C79N)(5-) has comparable stability with other better known iso electronic metallofullerene (C-80)(6-) cage species (e.g., Gd3N@C-80). These results describe an exceptionally stable paramagnetic molecule with low chemical reactivity with the unpaired electron spin density localized on the internal diatomic gadolinium cluster and not on the heterofullerene cage. EPR studies confirm that the spin state of Gd-2@C79N is characterized by a half-integer spin quantum number of S = 15/2. The spin (S =1/2) on the N atom of the fullerene cage and two octet spins (S = 7/2) of two encapsulated gadoliniums are coupled with each other in a ferromagnetic manner with a small zero-field splitting parameter D. Because the central line of Gd-2@C79N is due to the Kramer's doublet with a half-integer spin quantum number of S = 15/2, this relatively sharp line is prominent and the anisotropic nature of the line is weak. Interestingly, in contrast with most Gd3+ ion environments, the central EPR line (g = 1.978) is observable even at room temperature in a toluene solution. Finally, we report the first EHF derivative, a diethyl bromomalonate monoadduct of Gd-2@C79N, which was prepared and isolated via a modified Bingel-Hirsch reaction.
- リンク情報
- ID情報
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- DOI : 10.1021/ja202011u
- ISSN : 0002-7863
- Web of Science ID : WOS:000292439700031