2017年11月2日
Bis-Copper(II)/π-Radical Multi-Heterospin System with Non-innocent Doubly N-Confused Dioxohexaphyrin(1.1.1.1.1.0) Ligand
Chemistry - A European Journal
- 巻
- 23
- 号
- 61
- 開始ページ
- 15322
- 終了ページ
- 15326
- 記述言語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/chem.201704321
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim A contracted doubly N-confused dioxohexaphyrin(1.1.1.1.1.0) complex consisting of two paramagnetic copper metals and open-shell π-radical ligand was synthesized as a new multi-heterospin motif. X-ray spectroscopy supported the divalent character of the inner copper centers, and electron paramagnetic resonance and magnetometric studies suggested the presence of unpaired d electrons strongly antiferromagnetically coupled with π-radicals delocalized on the macrocycle. The 25 π non-innocent dioxohexaphyrin ligand allowed the facile interconversion between antiaromatic 24 π and aromatic 26 π species, respectively, upon redox reactions.
- リンク情報
- ID情報
-
- DOI : 10.1002/chem.201704321
- ISSN : 0947-6539
- eISSN : 1521-3765
- PubMed ID : 28906573
- SCOPUS ID : 85031105403