2012年2月
TIPSOTf-Promoted Tandem Reaction through Rearrangement of Epoxides into Aldehydes with Selective Alkyl Migration Followed by Prins-Type Cyclization to Cyclopentanes
SYNLETT
- ,
- ,
- ,
- ,
- 巻
- 号
- 3
- 開始ページ
- 458
- 終了ページ
- 462
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1055/s-0031-1290324
- 出版者・発行元
- GEORG THIEME VERLAG KG
The tandem reaction of trisubstituted epoxides to cyclopentanes promoted by TIPSOTf in nitromethane has been found. It consists of stereospecific rearrangement of epoxides into aldehydes accompanied with selective alkyl migration and subsequent Prins-type cyclization of the aldehydes generated to cyclopentanes.
- リンク情報
- ID情報
-
- DOI : 10.1055/s-0031-1290324
- ISSN : 0936-5214
- eISSN : 1437-2096
- Web of Science ID : WOS:000300711400027