2003年5月15日
Synthesis and characterization of mononuclear and tetranuclear palladium(II) complexes with 2-(phenylmethyleneamino)benzenethiolate
Inorganica Chimica Acta
- ,
- ,
- ,
- 巻
- 348
- 号
- 開始ページ
- 217
- 終了ページ
- 220
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1016/S0020-1693(02)01474-3
- 出版者・発行元
- Elsevier S.A.
Two palladium(II) complexes, [Pd(Hphbt-N,S)2] (1
Hphbt=2-(phenylmethyleneamino)benzenethiolate) and [Pd4(phbt-C,N,S)4] (2), were newly prepared. X-ray and 1H NMR studies indicated the presence of Pd⋯H-C interaction in the mononuclear 1, which is assumed to play an important role in the cyclometalation reaction leading to the tetranuclear structure in 2. © 2002 Elsevier Science B.V. All rights reserved.
Hphbt=2-(phenylmethyleneamino)benzenethiolate) and [Pd4(phbt-C,N,S)4] (2), were newly prepared. X-ray and 1H NMR studies indicated the presence of Pd⋯H-C interaction in the mononuclear 1, which is assumed to play an important role in the cyclometalation reaction leading to the tetranuclear structure in 2. © 2002 Elsevier Science B.V. All rights reserved.
- ID情報
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- DOI : 10.1016/S0020-1693(02)01474-3
- ISSN : 0020-1693
- SCOPUS ID : 0038732702