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Peer-reviewed Lead author Corresponding author
Jun, 2015

Correlations between Photovoltaic Characteristics, Adsorption Number, and Regeneration Kinetics in Dye-Sensitized Solar Cells Revealed by Scanning Photocurrent Microscopy

LANGMUIR
  • Masaaki Mitsui
  • ,
  • Yuya Kawano
  • ,
  • Kyosuke Mori
  • ,
  • Naoto Wakabayashi

Volume
31
Number
25
First page
7158
Last page
7165
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1021/acs.langmuir.5b01581
Publisher
AMER CHEMICAL SOC

Newly developed simultaneous scanning photocurrent and luminescence microscopy was applied to ruthenium-based dye-sensitized solar cells (DSCs) comprising a cover glass photoanode with a 100 nm thick TiO2 layer. Using this, we have investigated the lateral variations of several parameters of these DSCs under short-circuit conditions. Simultaneous measurement of photocurrent and luminescence images for the same area of the DSC demonstrated submicrometric lateral resolution of our photo current microscopy, which is approximately 10 times better than the resolution of photo current microscopy used in past studies. The photovoltaic parameters, such as short-circuit current density, open-circuit voltage, and charge-collection efficiency, were thus evaluated for local (or submicrometric) regions of the DSCs. Furthermore, the photocurrent saturation behavior of the DSCs was examined as a function of the excitation rate and analyzed on the basis of a three-state kinetic model. This protocol allowed for quantification of the dye-adsorption number and dye-regeneration rate constant for any local area of the DSCs. Consequently, the correlations between the dye adsorption number, photovoltaic parameters, and regeneration rate constant, which are difficult to address through examination of the entire cell, were revealed by the "zoom-in" approach utilizing this high-resolution photocurrent microscopy.

Link information
DOI
https://doi.org/10.1021/acs.langmuir.5b01581
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000357435600027&DestApp=WOS_CPL
ID information
  • DOI : 10.1021/acs.langmuir.5b01581
  • ISSN : 0743-7463
  • Web of Science ID : WOS:000357435600027

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