2005年9月
Formation and photoelectron spectroscopy of nanoscale cluster anions of biphenyl, (BP)(n)(-) (n=2-100)
CHEMISTRY LETTERS
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- 巻
- 34
- 号
- 9
- 開始ページ
- 1244
- 終了ページ
- 1245
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- 出版者・発行元
- CHEMICAL SOC JAPAN
Evolution of electronic structures of nanoscale biphenyl cluster anions, (BP)(n)(-) (n = 2-100), have been studied by photoelectron spectroscopy in a size-selective fashion. The energetics of vertical detachment energy (VDE) revealed negative electron affinity of a biphenyl molecule and substantial cluster reorganizations via electron attachment. Comparison of the VDE energetics with naphthalene cluster anions implied that the freezing (and/or melting) temperatures of the BP clusters may be much lower than those of naphthalene clusters.
- リンク情報
- ID情報
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- ISSN : 0366-7022
- eISSN : 1348-0715
- Web of Science ID : WOS:000231944500018