2013年
Characterization and catalytic properties in light olefin conversions of MFI type metallosilicate containing manganese or iron group metal prepared by rapid crystallization method
Journal of the Japan Petroleum Institute
- ,
- ,
- ,
- 巻
- 56
- 号
- 2
- 開始ページ
- 88
- 終了ページ
- 93
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1627/jpi.56.88
Metallosilicates containing manganese or iron group metals were prepared using a rapid crystallization method. The acidities of these metallosilicates and catalytic activities for the conversion of light olefins to gasoline fraction were investigated. The acidity and catalytic activity of the synthesized Mn-silicate did not depend on the manganese content. In contrast, the acid strengths and catalytic activities of metallosilicates containing iron group metals (iron-group-silicates) depended on the content and type of iron group metal. The acidity of the irongroup- silicates increased in the following order: Co-silicate<
Fe-silicate<
Ni-silicate. The selectivity for light paraffins and aromatic hydrocarbons over iron-group-silicates in conversion of light olefins increased in the same order. Consequently, Co-silicate had the lowest selectivity for aromatic hydrocarbons among all the iron-group-silicates for the conversion of light olefins into gasoline fraction.
Fe-silicate<
Ni-silicate. The selectivity for light paraffins and aromatic hydrocarbons over iron-group-silicates in conversion of light olefins increased in the same order. Consequently, Co-silicate had the lowest selectivity for aromatic hydrocarbons among all the iron-group-silicates for the conversion of light olefins into gasoline fraction.
- リンク情報
- ID情報
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- DOI : 10.1627/jpi.56.88
- ISSN : 1346-8804
- ISSN : 1349-273X
- SCOPUS ID : 84877719695