2013年5月
Photocatalytic Decomposition of Ethyl S-Diisopropylaminoethyl Methylphosphonothioate (VX) by Ag and Au Metal Deposited on TiO2 in Aqueous Phase
CHEMISTRY LETTERS
- 巻
- 42
- 号
- 5
- 開始ページ
- 518
- 終了ページ
- 520
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1246/cl.130015
- 出版者・発行元
- CHEMICAL SOC JAPAN
Ethyl S-diisopropylaminoethyl methylphosphonothioate (VX) in aqueous phase was decomposed by Ag- and Au-TiO2 photocatalyst. Photocatalytic decomposition rate, r(VX), was accelerated in the order of Ag-TiO2 > Au-TiO2 > bare TiO2 as a consequence of improving charge separation and increasing partial decomposition of VX molecular structure. It was suggested that the photocatalytic decomposition of VX molecule at the Au- and Ag-TiO2 was carried out by C-N, P-S cleavage and oxygenation.
- リンク情報
- ID情報
-
- DOI : 10.1246/cl.130015
- ISSN : 0366-7022
- eISSN : 1348-0715
- ORCIDのPut Code : 45677864
- Web of Science ID : WOS:000320418500021