2003年1月
Pd-catalyzed allylic substitution using nucleophilic N-heterocyclic carbene as a ligand
ORGANIC LETTERS
- ,
- ,
- 巻
- 5
- 号
- 1
- 開始ページ
- 31
- 終了ページ
- 33
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1021/ol026961v
- 出版者・発行元
- AMER CHEMICAL SOC
A nucleophilic N-heterocyclic carbene has been successfully used in a Pd(0)-catalyzed allylic substitution for the first time. It was found that allylic substitution with a soft nucleophile using a Pd-carbene catalyst proceeds via retention of configuration, the stereochemical reaction pathway being the same as that of the reaction using a Pd-phosphine complex.
- リンク情報
- ID情報
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- DOI : 10.1021/ol026961v
- ISSN : 1523-7060
- eISSN : 1523-7052
- Web of Science ID : WOS:000180240600009