MISC

2005年9月

Effect of polymer entanglement on the toughening of double network hydrogels

JOURNAL OF PHYSICAL CHEMISTRY B
  • H Tsukeshiba
  • ,
  • M Huang
  • ,
  • YH Na
  • ,
  • T Kurokawa
  • ,
  • R Kuwabara
  • ,
  • Y Tanaka
  • ,
  • H Furukawa
  • ,
  • Y Osada
  • ,
  • JP Gong

109
34
開始ページ
16304
終了ページ
16309
記述言語
英語
掲載種別
DOI
10.1021/jp052419n
出版者・発行元
AMER CHEMICAL SOC

The mechanical strength of double network (DN) gels consisting of highly cross-linked poly(2-acrylamido-2-methylpropanesulfonic acid) (PAMPS) as the first component and linear polyacrylamide (PAAm) as the second component has been investigated by varying the molecular weight of the second polymer PAAm, M-w. The experimental results reveal that, for toughening of the DN gels, (1) M-w is one of the dominant parameters, (2) there is a critical value of M-w = 10(6) for a remarkable enhancement: (3) the fracture energy of DN gels with a M-w, larger than 101 reaches a value as high as 10(3) J/m(2). By plotting the strength of DN gels (fracture stress sigma and fracture energy G) against a characteristic parameter of c[eta]. where c is the average concentration of PAAm in the DN gels and [eta] is the intrinsic viscosity of PAAm. it is found that the dramatic increase in the mechanical strength of the DN gels occurs above the region where linear PAAm chains are entangled with each other. Thus, we conclude that the entanglement between the second component PAAm plays an important role of the toughening mechanism of DN gels. This result supports the heterogeneous model, which predicts the presence of "voids" of the first network PAMPS with a size much larger than the radius of the second polymer PAAm.

リンク情報
DOI
https://doi.org/10.1021/jp052419n
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000231497500013&DestApp=WOS_CPL
ID情報
  • DOI : 10.1021/jp052419n
  • ISSN : 1520-6106
  • Web of Science ID : WOS:000231497500013

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