2014年7月
Abrupt Phase Transition Based on Electron-transfer-coupled Spin Transition in a Cyanide-bridged [Co2Fe2] Tetranuclear Complex
CHEMISTRY LETTERS
- ,
- ,
- 巻
- 43
- 号
- 7
- 開始ページ
- 1029
- 終了ページ
- 1030
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1246/cl.140248
- 出版者・発行元
- CHEMICAL SOC JAPAN
A cyanide-bridged tetranuclear complex, [Co2Fe2(CM6-(tP*)(2)(dmbPY)(4)](PF6)(2)center dot 4CH(3)CN (1 center dot 4CH(3)CN) (tp*: hydrotris-(3,5-dimethylpyrazol-1-yl)borate and dmbpy: 5,5'-dimethyl-2,2'-bipyridine), was synthesized and its magnetic properties were investigated. Magnetic susceptibility measurements revealed that 1 exhibited an abrupt one-step thermal phase transition based on electron-transfer-coupled spin transition (ETCST) and light-induced ETCST at low temperature.
- リンク情報
- ID情報
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- DOI : 10.1246/cl.140248
- ISSN : 0366-7022
- eISSN : 1348-0715
- Web of Science ID : WOS:000339364800021