2014年6月
Cyanide-Bridged Decanuclear Cobalt-Iron Cage
INORGANIC CHEMISTRY
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- 巻
- 53
- 号
- 12
- 開始ページ
- 5899
- 終了ページ
- 5901
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1021/ic500964m
- 出版者・発行元
- AMER CHEMICAL SOC
A cyanide-bridged decanuclear [Co6Fe4] cluster was synthesized by a one-pot reaction, and the magnetic properties and electronic configuration were investigated. The complex displayed thermally controlled electron-transfer-coupled spin transition (ETCST) behavior between Cow(III) low-spin-NC-Fen low-spin and Co-II high-spin-NC-Fe-III low-spin states, as confirmed by single-crystal X-ray, magnetic, and Mossbauer analyses.
- リンク情報
- ID情報
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- DOI : 10.1021/ic500964m
- ISSN : 0020-1669
- eISSN : 1520-510X
- Web of Science ID : WOS:000337557800009