2014年11月
Effect of Ring Sizes of Cyclooligosilanes on Construction of Organosilicon Clusters
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN
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- 巻
- 72
- 号
- 11
- 開始ページ
- 1290
- 終了ページ
- 1297
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.5059/yukigoseikyokaishi.72.1290
- 出版者・発行元
- SOC SYNTHETIC ORGANIC CHEM JPN
The degree of oligomerization in the Wurtz-type coupling of 1,1,2,2-tetrachlorocyclooligosilanes was found to be controlled by the ring sizes of the cyclooligosilanes. The Wurtz-type coupling of 1,1,2,2-tetrachlorocyclotetrasilane, -cyclopentasilane, and -cyclohexasilane gave a tetramer, a trimer, and a dimer, respectively. These oligomers are the first examples of octasilacuneane, hexasilabenzvalene, and bicyclo[4.1.0]heptasil-1(6)-ene derivatives.
- リンク情報
- ID情報
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- DOI : 10.5059/yukigoseikyokaishi.72.1290
- ISSN : 0037-9980
- Web of Science ID : WOS:000346691000011