MISC

2014年11月

Studies on the Detailed Structure of Poly(dimethylsilylene)

ORGANOMETALLICS
  • Soichiro Kyushin
  • ,
  • Keisuke Ichikawa
  • ,
  • Yu Koyama
  • ,
  • Hiroyuki Shiraiwa
  • ,
  • Hiroshi Ichikawa
  • ,
  • Kiyohito Okamura
  • ,
  • Kenji Suzuki

33
22
開始ページ
6298
終了ページ
6304
記述言語
英語
掲載種別
DOI
10.1021/om500264u
出版者・発行元
AMER CHEMICAL SOC

The detailed structure of poly(dimethylsilylene) was analyzed by Si-29 and 13C CP/MAS NMR spectra and theoretical calculations. The end groups were assigned to methoxy and hydroxy groups. This assignment was also supported by the NMR measurement of model compounds. Branched structures are not present. A trace amount of siloxane bonds is contained. The degree of polymerization was estimated to be ca. 580750 by the Si-29 CP/MAS NMR spectra.

リンク情報
DOI
https://doi.org/10.1021/om500264u
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000345552500008&DestApp=WOS_CPL
ID情報
  • DOI : 10.1021/om500264u
  • ISSN : 0276-7333
  • eISSN : 1520-6041
  • Web of Science ID : WOS:000345552500008

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