2014年11月
Studies on the Detailed Structure of Poly(dimethylsilylene)
ORGANOMETALLICS
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- 巻
- 33
- 号
- 22
- 開始ページ
- 6298
- 終了ページ
- 6304
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1021/om500264u
- 出版者・発行元
- AMER CHEMICAL SOC
The detailed structure of poly(dimethylsilylene) was analyzed by Si-29 and 13C CP/MAS NMR spectra and theoretical calculations. The end groups were assigned to methoxy and hydroxy groups. This assignment was also supported by the NMR measurement of model compounds. Branched structures are not present. A trace amount of siloxane bonds is contained. The degree of polymerization was estimated to be ca. 580750 by the Si-29 CP/MAS NMR spectra.
- リンク情報
- ID情報
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- DOI : 10.1021/om500264u
- ISSN : 0276-7333
- eISSN : 1520-6041
- Web of Science ID : WOS:000345552500008