2014年9月
Tetrasilane-Bridged Bicyclo[4.1.0]heptasil-1(6)-ene
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- ,
- ,
- 巻
- 136
- 号
- 37
- 開始ページ
- 12896
- 終了ページ
- 12898
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1021/ja507279z
- 出版者・発行元
- AMER CHEMICAL SOC
Tetrasilane-bridged bicyclo[4.1.0]heptasil-1(6)-ene 1 was synthesized by the reduction of 1,1,2,2-tetrachlorocyclohexasilane 2 in 12% yield as red-orange crystals. The structure and properties of 1 were studied by spectroscopy, X-ray crystallography, and theoretical calculations. The linkage of the cyclotrisilene moiety with two tetrasilane chains with tert-butyl groups remarkably affects its structure and Si-29 NMR spectrum.
- リンク情報
- ID情報
-
- DOI : 10.1021/ja507279z
- ISSN : 0002-7863
- eISSN : 1520-5126
- Web of Science ID : WOS:000342119700024