MISC

2004年3月

Diastereoselective formation of 2-fluoro-2-trifluoromethyl-3,4-alkadienamides from propargyl alcohols and hexafluoropropene-diethylamine adduct (PPDA)

JOURNAL OF FLUORINE CHEMISTRY
  • K Ogu
  • ,
  • M Akazome
  • ,
  • K Ogura

125
3
開始ページ
429
終了ページ
438
記述言語
英語
掲載種別
DOI
10.1016/j.jfluchem.2003.11.004
出版者・発行元
ELSEVIER SCIENCE SA

Treatment of propargyl alcohols (1) with hexafluoropropene-diethylamine adduct (PPDA) affords N,N-diethyl-2-fluoro-2-trifluoromethyl-3,4-alkadienamides (2) that are produced by the Claisen rearrangement of intermediary 2-alkynyl 1-(N,N-diethylamino)-2,3,3,3-tetrafluoro-1-propenyl ethers. Starting from propargyl alcohols bearing a triple bond at the terminal position, the corresponding products (2) were formed with a high stereoselectivity. (C) 2003 Elsevier B.V. All rights reserved.

Web of Science ® 被引用回数 : 6

リンク情報
DOI
https://doi.org/10.1016/j.jfluchem.2003.11.004
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000220050100010&DestApp=WOS_CPL
ID情報
  • DOI : 10.1016/j.jfluchem.2003.11.004
  • ISSN : 0022-1139
  • Web of Science ID : WOS:000220050100010

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