MISC

2004年12月

Crystalline inclusion compounds constructed through self-assembly of isonicotinic acid and thiocyanato coordination bridges

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  • R Sekiya
  • ,
  • S Nishikiori
  • ,
  • K Ogura

126
50
開始ページ
16587
終了ページ
16600
記述言語
英語
掲載種別
DOI
10.1021/ja0463280
出版者・発行元
AMER CHEMICAL SOC

The synthesis, crystal structures, inclusion ability, and structural robustness of novel crystalline inclusion compounds of [Ni(SCN)(2)(isoH)(2)].xG (isoH = isonicotinic acid; G = aromatic guest) are described. The inclusion compounds are constructed by stacking identical 2D host layers that consist of SCN-, isoH, and Ni2+ with van der Waals contact separation. In the layer, two types of rectangular cavities (A-type and B-type) are formed, and the guests are included in the former cavity. The inclusion compounds were categorized into four stacking modes according to the difference in the stacking mode of the layers. A systematic investigation of the crystal structures of the 21 inclusion compounds clarified the close relationship between the molecular structure of the guest and the resultant stacking mode of the layers.

Web of Science ® 被引用回数 : 50

リンク情報
DOI
https://doi.org/10.1021/ja0463280
CiNii Articles
http://ci.nii.ac.jp/naid/80017085408
PubMed
https://www.ncbi.nlm.nih.gov/pubmed/15600365
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000225808200065&DestApp=WOS_CPL
ID情報
  • DOI : 10.1021/ja0463280
  • ISSN : 0002-7863
  • CiNii Articles ID : 80017085408
  • PubMed ID : 15600365
  • Web of Science ID : WOS:000225808200065

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