2014年
Structural effects on the oxygen reduction reaction on the high index planes of Pt3Co
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
- ,
- ,
- 巻
- 16
- 号
- 27
- 開始ページ
- 13774
- 終了ページ
- 13779
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1039/c4cp00243a
- 出版者・発行元
- ROYAL SOC CHEMISTRY
The oxygen reduction reaction (ORR) has been studied on the n(111)-(111) and n(111)-(100) series of Pt3Co using a hanging meniscus rotating disk electrode (HMRDE) in 0.1 M HClO4 (n is the number of terrace atomic rows). The activity for the ORR on the n(111)-(111) series, which is estimated by the specific activity at 0.90 V (RHE) j(k), increases linearly with an increase in the step atom density d(S). On the other hand, the activity for the ORR on the n(111)-(100) series increases linearly with an increase of d(S) on the surfaces with n >= 9. On the surfaces with n < 9, however, the activity for the ORR decreases with an increase of d(S). We find a correlation between the ORR activity and theta(OH) at the step on the assumption that all the oxide species are Pt-OH.
- リンク情報
- ID情報
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- DOI : 10.1039/c4cp00243a
- ISSN : 1463-9076
- eISSN : 1463-9084
- Web of Science ID : WOS:000338116700027