2016年
Impregnation structure of cobalt ferrocyanide microparticles by the polymer chain grafted onto nylon fiber
JOURNAL OF NUCLEAR SCIENCE AND TECHNOLOGY
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- 巻
- 53
- 号
- 9
- 開始ページ
- 1251
- 終了ページ
- 1255
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1080/00223131.2016.1143886
- 出版者・発行元
- TAYLOR & FRANCIS LTD
At Tokyo Electric Power Company (TEPCO) Fukushima Daiichi nuclear power plant (NPP), water contaminated with radionuclides such as Cs-137 and Sr-90 has been stored in tanks and seawater-intake area. We have prepared cobalt-ferrocyanide-impregnated fibers via four steps: the grafting of an epoxy-group-containing monomer, the conversion of the epoxy group into positively charged groups, the binding of ferrocyanide ions ([Fe(CN)(6)](4-)), and the precipitation of cobalt ferrocyanide (Co-2[Fe(CN)(6)]) by contact with cobalt ions. However, the impregnation structure of cobalt ferrocyanide microparticles onto the fiber remains unclear. Here, we describe the impregnation structure from the results of rebinding [Fe(CN)(6)](4-) to the cobalt-ferrocyanide-impregnated fiber. The amount of [Fe(CN)(6)](4-) re-bound onto the fiber was found to decrease with increasing amount of Co-2[Fe(CN)(6)] initially impregnated. This suggests that the microparticles of cobalt ferrocyanide become entangled with the grafted polymer chains via multipoint electrostatic interactions.
- リンク情報
- ID情報
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- DOI : 10.1080/00223131.2016.1143886
- ISSN : 0022-3131
- eISSN : 1881-1248
- Web of Science ID : WOS:000380153600002