Papers

Peer-reviewed
2012

Unexpected formation of stannolanes and trigonal bipyramidal tin complexes by radical cyclization reaction

CHEMICAL COMMUNICATIONS
  • Akio Kamimura
    • ,
  • Shingo Ishikawa
    • ,
  • Fumiaki Noguchi
    • ,
  • Takaaki Moriyama
    • ,
  • Masahiro So
    • ,
  • Toshihiro Murafuji
    • ,
  • Hidemitsu Uno
Volume
48
Number
52
First page
6592
Last page
6594
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1039/c2cc31753b
Publisher
ROYAL SOC CHEMISTRY
Optically active stannolanes and trigonal bipyramidal penta-coordinated tin complexes were readily prepared by radical cyclization of N-propargylated chiral aza-Morita-Baylis-Hillman adducts induced by Bu3SnH. A translocated radical through the cyclization attacked the Bu3Sn group in an S(H)2 manner.
Link information
DOI
https://doi.org/10.1039/c2cc31753b
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000304883000042&DestApp=WOS_CPL
ID information
  • DOI : 10.1039/c2cc31753b
  • ISSN : 1359-7345
  • Web of Science ID : WOS:000304883000042
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