Apr, 2006
Chemical shifts in ESCA and NMR: The case of bridged trichlorosilyl-trimethylsilyl molecules
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
- ,
- ,
- Volume
- 79
- Number
- 4
- First page
- 537
- Last page
- 548
- Language
- English
- Publishing type
- Research paper (scientific journal)
- DOI
- 10.1246/bcsj.79.537
- Publisher
- CHEMICAL SOC JAPAN
A detailed examination of the relationship between chemical shifts in ESCA (electron spectroscopy for chemical analysis) and NMR (nuclear magnetic resonance) is presented for two silicon sites of bridged trichlorosilyl-trimethylsilyl molecules [Cl3Si-CnHm-Si(CH3)(3) (n = 0-5 and m = 0-10)]. It is shown that the ESCA chemical shift of a silicon site mainly depends on the electronic environment within a mean radius of 1.168 angstrom of the nucleus and the NMR chemical shift depends on the electronic environment within a radius of more than 1.875 angstrom.
- Link information
- ID information
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- DOI : 10.1246/bcsj.79.537
- ISSN : 0009-2673
- eISSN : 1348-0634
- CiNii Articles ID : 80019285879
- Web of Science ID : WOS:000237876100004