MISC

2015年

Dilute nitric or nitrous acid solution containing halide ions as effective media for pure gold dissolution

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
  • Masashi Hojo
  • ,
  • Masahiko Yamamoto
  • ,
  • Kei Okamura

17
30
開始ページ
19948
終了ページ
19956
記述言語
英語
掲載種別
DOI
10.1039/c5cp02288f
出版者・発行元
ROYAL SOC CHEMISTRY

The greatly enhanced oxidation ability of dilute aqueous nitric acid (0.10-2.0 mol L-1) containing bromide and iodide salts as well as chloride salts has been examined based on the dissolution kinetics of pure gold at 30-60 degrees C. It has been found that bromide salts are more effective than chloride salts in gaining the ability of dissolving gold in dilute aqueous nitric acid solution. At 60 degrees C, a piece of gold-wire (ca. 20 mg) is dissolved in 20 mL of as low as 0.10 mol L-1 HNO3 solution containing 1.0-5.0 mol L-1 NaBr and the dissolution rate constant, log(k/s(-1)), increases linearly (from -5.78 to -4.52) with the increasing NaBr concentration. The addition of organic solvents, such as acetonitrile and acetic acid, causes acceleration of gold dissolution in LiBr and NaBr solutions. With increasing MeCN contents, for instance, the log(k/s(-1)) value of 0.10 mol L-1 HNO3 solution containing 2.0 mol L-1 NaBr increases linearly from -5.30 to -4.61 at 30% (v/v) MeCN. The bromide salts affect the gold dissolution rate constant in the order of KBr < NaBr < LiBr < CaBr2. With increasing NaI concentration (0.20-3.0 mol L-1), some acceleration in log(k/s(-1)) of 0.50 or 1.0 mol L-1 HNO3 solution has been observed; however, the slope of acceleration as the function of NaI concentration is much smaller than that of NaCl or NaBr. The gold dissolution ability has been examined also for nitrous acid containing chloride and bromide ions at 35 degrees C. The NaNO2 solution containing twice or more amounts of HX (X = Cl, Br) gives the maximum efficiency for gold dissolution, according to the log(k/s(-1)) values of the mixed solutions of NaNO2 (0.10-2.0 mol L-1) and HX of various concentrations. The influence of oxidation by dilute nitric and nitrous acids on the gold dissolution is discussed from the standpoint of the redox potentials in "modified'' aqueous solutions and not of the changes in the activity coefficients of ions.

リンク情報
DOI
https://doi.org/10.1039/c5cp02288f
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000358347500030&DestApp=WOS_CPL
ID情報
  • DOI : 10.1039/c5cp02288f
  • ISSN : 1463-9076
  • eISSN : 1463-9084
  • Web of Science ID : WOS:000358347500030

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