金政修司 (Shuji Kanemasa) - マイポータル

基本情報

所属: 旧所属九州大学先導物質化学研究所物質基盤化学部門教授

学位: 工学博士

J-GLOBAL ID: 200901072471569711
researchmap会員ID: 1000041735

外部リンク: http://www.cm.kyushu-u.ac.jp/dv01/dv01j.html

研究キーワード

研究分野

ナノテク・材料 / 有機合成化学 /

学歴

MISC

Enantioselective Michael additions of nitromethane by a catalytic double activation method using chiral Lewis acid and achiral amine catalysts

K Itoh, S Kanemasa

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 124(45) 13394-13395 2002年11月
Nitrone Cycloaddition Reactions to a,b-Unsaturated carbonyl Acceptors Catalyzed by a Pinhole Lewis Acid Catalyst. Dramatic Rate Acceleration and Improvement of Regioselectivity and Diastereoselectivity

Tetrahedron Lett. 43, 4, 657-660 2002年
Enantioselective Conjugate Additions of Aldoximes to 3-Crotonoyl-2-oxazolidinone and 1-Crotonoyl-3-phenyl-2-imidazolidinone Catalyzed by the Aqua Complex between R,R-DBFOX/Ph and Zinc(II) Perchlorate

Tetrahedron Lett. 43, 5, 829-832 2002年
Enantioselective preparation of 3,4,5-trisubstituted 4,5-dihydroisoxazoles and their stereoselective elaboration of 5-side chain

Tetrahedron 58, 47, 9613-9620 2002年
Metal-Assisted Stereocontrol of 1,3-Dipolar Cycloaddition Reactions

Synlett 2002, 9, 1371-1387 2002年
Ab initio study of Lewis acid catalyzed nitrone cycloaddition to electron deficient alkenes. Does a Lewis acid catalyst change the reaction mechanism?

Tetrahedron 57, 5, 899-905 2001年
A New Synthetic Access to N-Alkylated Nitrones through Lewis Acid-Catalyzed Conjugate Additions of Aldoximes

Tetrahedron Lett. 42, 38, 6719-6722 2001年
A Novel Tandem Transetherification-Intramolecular Hetero Diels-Alder Reactions for Construction of Fused Heterocycles

Tetrahedron Lett. 41, 1, 73-76 2000年
Synthesis of Hydroximoyl Chlorides from Aldoximes and Benzyltrimethylammonium Tetrachloroiodate (BTMA ICl4)

Tetrahedron 56, 8, 1057-1064 2000年
ルイス酸触媒下での 1,3-双極性環状付加反応の立体化学制御−ニトロンおよびニトロナート環状付加

日本化学会誌 2000, 3, 155-165 2000年
Bisoxazoline and Bioxazoline Chiral Ligands Bearing 4-Diphenylmethyl Shielding Substituents. Diels-Alder Reaction of Cyclopentadiene with 3-Acryloyl-2-oxazolidinone Catalyzed by the Aqua Nickel(II) Complex

Bull. Chem. Soc. Jpn. 73, 3, 681-687 2000年
An ab initio Molecular Orbital Study on the Magnesium Controlled 1,3-Cycloaddition of Nitrile Oxides and Allylic Alcohols with Regio- and Stereoselectivity

Tetrahedron 56, 12, 1637-1647 2000年
Metal Ion-Mediated Diastereoface-Selective 1,3-Dipolar Cycloaddition of Nitrile Oxides with Dipolarophiles Bearing an Oxazolidinone Chiral Auxiliary

Tetrahedron Lett. 41, 17, 3131-3136 2000年
Lewis Acid - Catalyzed Enantioselective 1,3-Dipolar Cycloadditions of Diazoalkane: Chiral Ligand / Achiral Auxiliary Coorperative Chirality Control

J. Am. Chem. Soc. 122, 43, 10710-10711 2000年
Enantioselective Conjugate Radical Addition Reactions Mediated by Chiral Lewis Acid Complexes of (R,R)-4,6-Dibenzofurandiyl-2,2'-bis(4-phenyloxazoline) (DBFOX/Ph)

Tetrahedron Asymm. 10, 12, 2417-2428 1999年
Enantioselective Preparation of 3,4,5-Trisubstituted -4,5-dihydroisoxazoles and 4-Substituted-5,6-dihydro-4H-[1,2]-Oxazines by Nitrile Oxide Cycloaddition to a-Silyl Allyl Alcohols

Tetrahedron Lett. 40, 23, 4349-4352 1999年
Lewis Acid-Catalyzed Reactions of Ethyl Diazoacetate with Aldehydes. Synthesis of a-Formyl Esters by a Sequence of Aldol Reaction and 1,2-Nucleophilic Rearrangement

Tetrahedron Lett. 40, 27,5055-5058 1999年
Fluoride-Catalyzed Aldol Reaction of Ethyl Trimethylsilyldiazoacetate with Aldehydes Leading to Ethyl a-Diazo-b-hydroxy Esters and Rhodium Catalyzed Decarboxylative Rearrangement of Diazo Urethanes Leading to b-Amino Acrylates

Tetrahedron Lett. 40, 27, 5059-5062 1999年
Asymmetric Conjugate Addition of Thiols to 3-(2-Alkenoyl)-2-oxazolidinones Catalyzed by the DBFOX/Ph Aqua Complex of Nickel(II) Perchlorate

J. Am. Chem. Soc. 121, 37, 8675-8676 1999年
Asymmetric Conjugate Addition of Thiols to a 3-(2-Alkenoyl)-2-oxazolidinone Catalyzed by the DBFOX/Ph Aqua Complex of Nickel((]G0002[)) Perchlorate

J. Am. Chem. Soc. 121(37) 8675-8676 1999年

もっとみる

書籍等出版物

Effect of external reagents as a Chapter of "Synthetic Applications of 1,3-Dipolar Cycloaddition Chemistry toward Heterocycles and Natural Products" as Volume 59 of "Chemistry of Heterocyclic Compounds"

Effect of External Reagets (Chap. 11), Synthetic Application of 1,3-Dipolar Cycloaddition Chemistry Toward Heterocycles and Natural Products (Vol. 59 of The Chemistry of Heterocyclic Compounds), ed by A. Padwa and W. Pearson 2002年
Aqua Complex Lewis Acid Catalysts for Asymmtric 3+2 Cycloaddition Reactions

Chapter 7 in "Cycloaddition Reactions in Organic Synthesis", ed. S. Kobayashi, S.; Jorgensen, K. A., Wiley-VCH 2001年
N-Metalated Azomethine Ylides

JAI Press, Inc. 1992年
Recent Advances in Azomethine Ylide Chemistry

Academic Press, Inc. 1989年

金政修司

基本情報

研究キーワード

研究分野

学歴

MISC

書籍等出版物

所属学協会

共同研究・競争的資金等の研究課題

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