MISC

1999年11月

Intermolecular excimer formation in dinuclear metal complexes

CHEMISTRY LETTERS
  • Y Yano
  • ,
  • K Hino
  • ,
  • R Nakata
  • ,
  • H Sekiya
  • ,
  • Y Maeda

11
開始ページ
1151
終了ページ
1152
記述言語
英語
掲載種別
DOI
10.1246/cl.1999.1151
出版者・発行元
CHEMICAL SOC JAPAN

In this paper the intramolecular/intermolecular excimer formations of [Fe-2(bpmp)(1-pyace)(2)](BF4)(2) [ZnFe(bpmp)(1-pyace)(2)](ClO4)(2) and [Zn-2(bpmp)(1-pyace)(2)]ClO4 which contain 1-pyreneacetic acid as a chromophore are reported. The fluorescent properties of the ZnZn complex offer the intramolecular dimers of the two chromophores in addition to intermolecular dimers due to the intermolecular stacking. The ZnFe and FeFe complexes are under the strong influence of quenching and show weak intramolecular/intermolecular excimer formation in the concentration more than 10(-4) M. The emission intensities and intensity ratios (I-E/I-M) of the fluorescence are dependent on the metal ions.

リンク情報
DOI
https://doi.org/10.1246/cl.1999.1151
CiNii Articles
http://ci.nii.ac.jp/naid/10005719072
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000083863000010&DestApp=WOS_CPL
ID情報
  • DOI : 10.1246/cl.1999.1151
  • ISSN : 0366-7022
  • eISSN : 1348-0715
  • CiNii Articles ID : 10005719072
  • Web of Science ID : WOS:000083863000010

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