2021年10月16日
Supramolecular assembly of glutamide attached terpyridine-lanthanide complex with enhanced chirality and high fluorescence quantum yield
Chemical Physics Letters
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- 巻
- 781
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- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1016/j.cplett.2021.138968
- 出版者・発行元
- ELSEVIER
A L-glutamide attached terpyridine (G-tpy) enhanced lanthanide supramolecular assembly (G-tpy+Ln3+) (Ln3+ = Eu3+ and Tb3+) was fabricated in a facile but efficient way in a mixed solvent of cyclohexane-ethanol (9:1). Significantly, the resultant fibrous assembly could show remarkable enhancement through coordination-driven secondary chirality of molecular gels at 1:1 stichometry of G-tpy+Ln3+ ratio. Furthermore, this system showed high fluorescence quantum yield of 25.5% and 32.7% with Eu3+ and Tb3+ in cyclohexane-ethanol. This type of G-tpy+Ln3+ self-assembly can be inherently applicable in sensing or bioimaging technology because of their multiple-stimuli responsive behaviour.
- リンク情報
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- DOI
- https://doi.org/10.1016/j.cplett.2021.138968
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000703620000005&DestApp=WOS_CPL
- Scopus
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85112797801&origin=inward
- Scopus Citedby
- https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85112797801&origin=inward
- ID情報
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- DOI : 10.1016/j.cplett.2021.138968
- ISSN : 0009-2614
- eISSN : 1873-4448
- SCOPUS ID : 85112797801
- Web of Science ID : WOS:000703620000005