MISC

1999年5月

Measurement and correlation of isoprene-maleic anhydride reaction rate in hexane-nitrobenzene mixture

KAGAKU KOGAKU RONBUNSHU
  • Y Inoue
  • ,
  • T Nishikawa
  • ,
  • M Sato
  • ,
  • Y Iwai
  • ,
  • Y Arai
  • ,
  • H Kato

25
3
開始ページ
491
終了ページ
493
記述言語
日本語
掲載種別
DOI
10.1252/kakoronbunshu.25.491
出版者・発行元
SOC CHEMICAL ENG JAPAN

Reaction rates for the Diels-Alder reaction of isoprene with maleic anhydride in the hexane-nitrobenzene mixed solvent were measured at 308.15 K. By using a reaction rate equation derived from the transition state theory coupled with the regular solution model, the reaction rates obtained previously at 293.88 K and in the present study were correlated. The dependence of reaction rates on the composition of hexane-nitrobenzene mixed solvent was correlated with fairly good agreement by introducing interaction parameters estimated with vapor-liquid equilibria into the regular solution model.

リンク情報
DOI
https://doi.org/10.1252/kakoronbunshu.25.491
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000081523300027&DestApp=WOS_CPL
ID情報
  • DOI : 10.1252/kakoronbunshu.25.491
  • ISSN : 0386-216X
  • Web of Science ID : WOS:000081523300027

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