1999年5月
Measurement and correlation of isoprene-maleic anhydride reaction rate in hexane-nitrobenzene mixture
KAGAKU KOGAKU RONBUNSHU
- ,
- ,
- ,
- ,
- ,
- 巻
- 25
- 号
- 3
- 開始ページ
- 491
- 終了ページ
- 493
- 記述言語
- 日本語
- 掲載種別
- DOI
- 10.1252/kakoronbunshu.25.491
- 出版者・発行元
- SOC CHEMICAL ENG JAPAN
Reaction rates for the Diels-Alder reaction of isoprene with maleic anhydride in the hexane-nitrobenzene mixed solvent were measured at 308.15 K. By using a reaction rate equation derived from the transition state theory coupled with the regular solution model, the reaction rates obtained previously at 293.88 K and in the present study were correlated. The dependence of reaction rates on the composition of hexane-nitrobenzene mixed solvent was correlated with fairly good agreement by introducing interaction parameters estimated with vapor-liquid equilibria into the regular solution model.
- リンク情報
- ID情報
-
- DOI : 10.1252/kakoronbunshu.25.491
- ISSN : 0386-216X
- Web of Science ID : WOS:000081523300027