1998年
Dissociation of metastable CH3CO radical studied by time-resolved photofragment imaging
LASER TECHNIQUES FOR STATE-SELECTED AND STATE-TO-STATE CHEMISTRY IV
- ,
- ,
- 巻
- 3271
- 号
- 開始ページ
- 2
- 終了ページ
- 6
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1117/12.308393
- 出版者・発行元
- SPIE-INT SOC OPTICAL ENGINEERING
A novel experimental technique to measure the energy-dependent unimolecular dissociation rate k(E) of radical species is presented. Internally excited CH3CO radicals were formed by ultraviolet photodissociation of CH3COCl, and the subsequent decay of these radicals was detected by subpicosecond time-clocked photofragment imaging. The CH3CO radicals with different internal energies were dispersed in space by their recoil velocities, and their decay rates were measured for each internal energy.
- リンク情報
- ID情報
-
- DOI : 10.1117/12.308393
- ISSN : 0277-786X
- Web of Science ID : WOS:000074380900001