MISC

1991年11月

STEREOCONTROLLED INTRAMOLECULAR CYCLIZATION OF OMEGA-TRIBUTYLSTANNYL ETHER ALDEHYDES - SYNTHESIS OF THE 6.7.7.6 RING-SYSTEM OF POLYCYCLIC ETHERS

TETRAHEDRON LETTERS
  • Y YAMAMOTO
  • ,
  • J YAMADA
  • ,
  • KADOTA, I

32
48
開始ページ
7069
終了ページ
7072
記述言語
英語
掲載種別
DOI
10.1016/0040-4039(91)85042-4
出版者・発行元
PERGAMON-ELSEVIER SCIENCE LTD

The BF3.OEt2 mediated intramolecular cyclization of the gamma-oxo-substituted allylic tin (1) having an aldehyde group at the terminus of the carbon chain proceeded in a stereocontrolled manner to give the 7-membered beta-hydroxy cyclic ether (2a) with high diastereoselectivity. This method was applied for the synthesis of the 6.7.7.6 ring system (3a).

リンク情報
DOI
https://doi.org/10.1016/0040-4039(91)85042-4
CiNii Articles
http://ci.nii.ac.jp/naid/80006220984
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:A1991GU56800021&DestApp=WOS_CPL
ID情報
  • DOI : 10.1016/0040-4039(91)85042-4
  • ISSN : 0040-4039
  • CiNii Articles ID : 80006220984
  • Web of Science ID : WOS:A1991GU56800021

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