2018年4月15日
Improved Synthesis of the A–E Ring Segment of Ciguatoxin CTX3C by Using Intramolecular Allylations
Bulletin of the Chemical Society of Japan
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- 巻
- 91
- 号
- 4
- 開始ページ
- 507
- 終了ページ
- 514
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1246/bcsj.20170390
- 出版者・発行元
- The Chemical Society of Japan
An improved synthesis of the AE ring segment of ciguatoxin CTX3C is described. The E ring segment was synthesized by the intramolecular reaction of allylic stannane and aldehyde with high stereoselectivity. Construction of the AE ring framework was performed by using the intramolecular allylation of α-acetoxy ether followed by ring-closing metathesis.
- リンク情報
- ID情報
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- DOI : 10.1246/bcsj.20170390
- ISSN : 0009-2673
- eISSN : 1348-0634
- SCOPUS ID : 85045473993