2005年3月
Stereoselective synthesis of multisubstituted alkenes via conformationally labile alkenyllithium species
ORGANIC LETTERS
- ,
- ,
- ,
- ,
- 巻
- 7
- 号
- 5
- 開始ページ
- 909
- 終了ページ
- 911
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1021/ol0501141
- 出版者・発行元
- AMER CHEMICAL SOC
Stereoselective synthesis of tri- and tetrasubstituted alkenylsilanes has been realized by the selective intramolecular silicon migration in the rapidly equilibrating alkenyllithium species. Subsequent copper- and palladium-mediated coupling with allyl and aryl halides provides tri- and tetrasubstituted alkenes possessing all different carbon-substituents with complete stereoselectivity.
- リンク情報
- ID情報
-
- DOI : 10.1021/ol0501141
- ISSN : 1523-7060
- ORCIDのPut Code : 33843358
- Web of Science ID : WOS:000227313400041