2011年10月
Synthesis of Well-defined Amphiphilic Block Copolymers by Organotellurium-Mediated Living Radical Polymerization (TERP)
MACROMOLECULAR RAPID COMMUNICATIONS
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- 巻
- 32
- 号
- 19
- 開始ページ
- 1576
- 終了ページ
- 1582
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/marc.201100277
- 出版者・発行元
- WILEY-BLACKWELL
Low-molecular weight amphiphilic diblock copolymers, polystyrene-block-poly (2-vinylpyridine) (PS-b-P2VP), and (P2VP-b-PS) with different block ratios were synthesized for the first time via organotellurium-mediated living radical polymerization (TERP). For both the homo- and block copolymerizations, good agreement between the theoretical, and experimental molecular weights was found with nearly 100% yield in every case. The molecular weight distribution for all the samples ranged between 1.10 and 1.24, which is well below the theoretical lower limit of 1.50 for a conventional free radical polymerization. Furthermore, a very simple approach to producing highly dense arrays of titania nanoparticles (TiO(2)) is presented using a site-selective reaction of titanium tetraisopropoxide within the P2VP domains of micellar film of P2VP-b-PS in toluene through the sol-gel method.
- リンク情報
- ID情報
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- DOI : 10.1002/marc.201100277
- ISSN : 1022-1336
- J-Global ID : 201102287621417174
- Web of Science ID : WOS:000295335200011