2007年9月
Electrochemical performance of LiFePO(4) modified by pressure-pulsed chemical vapor infiltration in lithium-ion batteries
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY
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- 巻
- 142
- 号
- 2-3
- 開始ページ
- 86
- 終了ページ
- 92
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1016/j.mseb.2007.07.003
- 出版者・発行元
- ELSEVIER SCIENCE SA
Using the pressure-pulsed chemical vapor infiltration (PCVI) technique, pyrolytic carbon (pyrocarbon) films were deposited on the surface of LiFePO(4) particles for cathode material of lithium-ion batteries. The electrochemical performance of the original LiFePO(4) and PCVIed LiFePO(4) materials was evaluated using a three electrodes cell by galvanostatic charging/discharging at 25, 40 and 55 degrees C, respectively. Morphology and structure of LiFePO(4) were analyzed by SEM, XRD and Raman. The resulting carbon contents at 500, 1000, 2000, 3000 and 5000 pulses were 2.7, 4.7, 9.5, 15.1 and 19.4%, respectively and these samples were abbreviated as 500P, 1000P, 2000P, 3000P and 5000P, respectively. All the PCVIed samples exhibited excellent rate performance. The tendency was more and more obvious with the increase of the current densities. The specific capacities of 500P, 1000P and 2000P were maintained at 117, 124 and 132 mAh g(-1), respectively, which were 120.8, 264.7 and 29.47% larger than those of corresponding original LiFePO(4), respectively, at a 5C rate at 55 degrees C. The EIS measurement showed that electrochemical reaction resistance (R(ct)) of PCVIed LiFePO(4) were obviously decreased, indicating a fast kinetics compared to the original LiFePO(4). The cycle ability of the 2000P sample was tested at 25 degrees C and C/2 rate. The cell was cycled for 150 cycles and no obviously capacity fade was observed. Its specific capacity of 115 mAh g(-1) at 150th cycle is 1.7 times higher than that of original LiFePO(4) (c) 2007 Elsevier B.V. All rights reserved.
- リンク情報
- ID情報
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- DOI : 10.1016/j.mseb.2007.07.003
- ISSN : 0921-5107
- CiNii Articles ID : 80018233839
- Web of Science ID : WOS:000250251000005