1994年5月
MAGNETIC CHARACTERIZATION AND COMPUTATIONAL MODELING OF POLY(PHENYLACETYLENE)S BEARING STABLE RADICAL GROUPS
MACROMOLECULES
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- 巻
- 27
- 号
- 11
- 開始ページ
- 3082
- 終了ページ
- 3086
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/ma00089a027
- 出版者・発行元
- AMER CHEMICAL SOC
The magnetic properties of poly(phenylacetylene)s with radical groups at the paraposition, poly[(3,5-di-tert-butyl-4-oxyphenyl)acetylene] (1),poly[[4-[(3,5-di-tert-butyl-4-oxyphenyl)(3,5-di-tert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)methyl]phenyl]acetylene] (2), and poly[[4-(N-tert-butyl-N-oxyamino)phenyl]acetylene] (3), were studied with a SQUID magnetometer. The magnetization and magnetic susceptibility indicated unexpected antiferromagnetic interactions between the radical sites. The exchange interaction observed in these conjugated polyradicals was discussed in connection with their computationally modeled structures.
- リンク情報
- ID情報
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- DOI : 10.1021/ma00089a027
- ISSN : 0024-9297
- eISSN : 1520-5835
- Web of Science ID : WOS:A1994NP31100027