Papers

Peer-reviewed
Sep, 2012

A Perturbation Theory for Friction of a Large Particle Immersed in a Binary Solvent

JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN
  • Yuka Nakamura
  • ,
  • Akira Yoshimori
  • ,
  • Ryo Akiyama

Volume
81
Number
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1143/JPSJS.81SA.SA026
Publisher
PHYSICAL SOC JAPAN

A new theory of a binary solvent is developed to study the effects of the density of solvent particles around a large solute particle on friction. To develop the theory, the solvent particles are assumed to be much smaller than the solute particle, and then a perturbation expansion is employed. The expansion allows one to derive hydrodynamic equations with boundary conditions on the surface of a solute. The boundary conditions are calculated from the radial distribution functions of a binary solvent. The hydrodynamic equations with the boundary conditions provide an analytical expression for the friction. The developed theory is applied to a binary hard-sphere system. The present theory shows that the friction in the system has larger values than those predicted by the Stokes law.

Link information
DOI
https://doi.org/10.1143/JPSJS.81SA.SA026
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000208846400027&DestApp=WOS_CPL
ID information
  • DOI : 10.1143/JPSJS.81SA.SA026
  • ISSN : 0031-9015
  • Web of Science ID : WOS:000208846400027

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