2019年12月2日
Bulky Substituent Effect on Reactivity of Localized Singlet Cyclopentane-1,3-diyls with π-Single Bonding (C-π-C) Character
Chemistry - An Asian Journal
- ,
- 巻
- 14
- 号
- 23
- 開始ページ
- 4223
- 終了ページ
- 4228
- 記述言語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/asia.201901253
Thorough investigation of key intermediates, such as long-lived singlet diradicals, is essential to understand the homolytic bond cleavage reactions. In this study, we evaluate the effect of bulky substituents at the meta-position of the phenyl ring on the bond formation process in singlet 2,2-diethoxy-1,3-diarylcyclopentane-1,3-diyls. The bulky groups have significant influence on the diradical lifetime, as such, when the triisopropylphenyl group was used, the lifetime was 45 times longer than that of the parent diradical in benzene at 293 K.
- リンク情報
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- DOI
- https://doi.org/10.1002/asia.201901253
- PubMed
- https://www.ncbi.nlm.nih.gov/pubmed/31583855
- Scopus
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85074556147&origin=inward 本文へのリンクあり
- Scopus Citedby
- https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85074556147&origin=inward
- ID情報
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- DOI : 10.1002/asia.201901253
- ISSN : 1861-4728
- eISSN : 1861-471X
- PubMed ID : 31583855
- SCOPUS ID : 85074556147