論文

査読有り 本文へのリンクあり 国際共著
2019年3月

Na2Ru1-xMnxO3 as the cathode for sodium-ion batteries

JOURNAL OF MATERIALS CHEMISTRY A
  • Li, Xiang
  • ,
  • Guo, Shaohua
  • ,
  • Qiu, Feilong
  • ,
  • Wang, Linlin
  • ,
  • Ishida, Masayoshi
  • ,
  • Zhou, Haoshen

7
9
開始ページ
4395
終了ページ
4399
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1039/c8ta11915e
出版者・発行元
ROYAL SOC CHEMISTRY

Sodium-ion batteries (SIBs) have attracted a surge of attention as a potential alternative for replacing lithium-ion batteries (LIBs). However, the current cathodes of SIBs suffer from problems of limited capacity, capacity decay, inferior cycling performance and structural instability. Na2RuO3 is known for its high capacity including both cationic redox and anionic redox processes. Here, we show a general method for improving the sodium storage performance of Na(2)RuO(3)via Mn doping. A series of Na2Ru1-xMnxO3 are explored through X-ray diffraction (XRD), galvanostatic charge-discharge testing, electrochemical impedance spectroscopy (EIS) measurements and so on. The results exhibit that a suitable Mn doping (x = 0.1) enhances the kinetics and structural stability of the electrode, accounting for a superior electrochemical performance. Our findings provide a simple method to develop advanced cathodes for SIBs with a long lifespan and large capacity.

リンク情報
DOI
https://doi.org/10.1039/c8ta11915e
URL
http://hdl.handle.net/2241/00157333 本文へのリンクあり
ID情報
  • DOI : 10.1039/c8ta11915e
  • ISSN : 2050-7488

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