2016年4月
SYNTHESIS OF A NEW CHIRAL C-2-SYMMETRIC NHC-AuCl COMPLEX
HETEROCYCLES
- ,
- ,
- ,
- 巻
- 92
- 号
- 4
- 開始ページ
- 720
- 終了ページ
- 732
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.3987/COM-16-13408
- 出版者・発行元
- PERGAMON-ELSEVIER SCIENCE LTD
A New chiral C-2 symmetric NHC ligand with two binaphthyl units has been synthesized. The new NHC ligand features two seven-membered rings that link the imidazolylidene with the binaphthyl units. X-Ray crystallographic analysis of the new NHC-AuCl complex indicates that the Au-Cl bond is located between the phenyl groups of the binaphthyl units and suggests that this arrangement could induce enantioselectivity in reactions. Indeed, catalytic asymmetric ene-yne cyclization of 2b in the presence of a catalytic amount (5 mol%) of cationic complex of 13 quantitatively afforded the cyclized product with 78% ee.
- リンク情報
- ID情報
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- DOI : 10.3987/COM-16-13408
- ISSN : 0385-5414
- eISSN : 1881-0942
- Web of Science ID : WOS:000375511100010