MISC

2008年4月

Catalytic decomposition of biomass tars with iron oxide catalysts

FUEL
  • Md. Azhar Uddin
  • ,
  • Hiroshi Tsuda
  • ,
  • Shengji Wu
  • ,
  • Eiji Sasaoka

87
4-5
開始ページ
451
終了ページ
459
記述言語
英語
掲載種別
DOI
10.1016/j.fuel.2007.06.021
出版者・発行元
ELSEVIER SCI LTD

Catalytic gasification of wood (Cedar) biomass was carried out using a specially designed flow-type double beds micro reactor in a two step process: temperature programmed non-catalytic steam gasification of biomass was performed in the first (top) bed at 200-850 degrees C followed by catalytic decomposition gasification of volatile matters (including tars) in the second (bottom) bed at a constant temperature, mainly 600 degrees C. Iron oxide catalysts, which transformed to Fe3O4 after use possessed catalytic activity in biomass tar decomposition. Above 90% of the volatile matters was gasified by the use of iron oxide catalyst (prepared from FeCl3 and NH3aq) at SV of 4.5 x 10(3) h(-1). Tar was decomposed over the iron oxide catalysts followed by water gas shift reaction. Surface area of the iron oxide seemed to be an important factor for the catalytic tar decomposition. The activity of the iron oxide catalysts for tar decomposition seemed stable with cyclic use but the activity of the catalysts for the water gas shift reaction decreased with repeated use. (c) 2007 Elsevier Ltd. All rights reserved.

リンク情報
DOI
https://doi.org/10.1016/j.fuel.2007.06.021
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000253332200005&DestApp=WOS_CPL
ID情報
  • DOI : 10.1016/j.fuel.2007.06.021
  • ISSN : 0016-2361
  • Web of Science ID : WOS:000253332200005

エクスポート
BibTeX RIS