論文

査読有り 筆頭著者 責任著者
2018年4月

Phase relationships of the system Fe-Ni-S and structure of the high-pressure phase of (Fe1-xNix)(3)S-2

PHYSICS OF THE EARTH AND PLANETARY INTERIORS
  • Satoru Urakawa
  • ,
  • Ryota Kamuro
  • ,
  • Akio Suzuki
  • ,
  • Takumi Kikegawa

277
開始ページ
30
終了ページ
37
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1016/j.pepi.2018.01.007
出版者・発行元
ELSEVIER

The phase relationships of the Fe-Ni-S system at 15 GPa were studied by high pressure quench experiments. The stability fields of (Fe,Ni)(3)S and (Fe,Ni)(3)S-2 and the melting relationships of the Fe-Ni-S system were determined as a function of Ni content. The (Fe,Ni)(3)S solid solution is stable in the composition of Ni/(Fe + Ni) > 0.7 and melts incongruently into an Fe-Ni alloy + liquid. The (Fe,Ni)(3)S-2 makes a complete solid solution and melts incongruently into (Fe,Ni)S + liquid, whose structure was determined to show Cmcm-orthorhombic symmetry by in situ synchrotron X-ray diffraction experiments. The eutectic contains about 30 at.% of S, and its temperature decreases with increasing Ni content with a rate of similar to 5 K/at.% from 1175 K. The density of the Fe-FeS eutectic composition (Fe70S30) liquid is evaluated to be 6.93 +/- 0.08 g/cm(3) at 15 GPa and 1200 K based on the Clausius-Clapeyron relations and densities of subsolidus phases. The Fe-Ni-S liquids are a primary sulfur-bearing phase in the deep mantle with a reducing condition (250-660 km depth), and they would play a significant role in the carbon cycle as a carbon host as well as in the generation of diamond.

リンク情報
DOI
https://doi.org/10.1016/j.pepi.2018.01.007
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000430996200003&DestApp=WOS_CPL
ID情報
  • DOI : 10.1016/j.pepi.2018.01.007
  • ISSN : 0031-9201
  • eISSN : 1872-7395
  • Web of Science ID : WOS:000430996200003

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